Forskning ved Københavns Universitet - Københavns Universitet


(1R,2R)-4-Benzoyl-2-benzoyloxy-1-phenylbutyl imidazole-1-carboxylate

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningfagfællebedømt

  • D.J. Fox
  • S. Parris
  • Daniel Sejer Pedersen
  • S. Warren
The title compound, C28H24N2O5, was prepared from (E)-2-cinnamyl-1,3- diphenyl-propane-1,3-dione using standard Sharpless asymmetric dihydroxy-lation conditions, followed by treatment with 1,1′-carbonyl diimidazole. In the crystal structure, the phenyl rings form inter-molecular face-to-face π-π contacts, with an inter-planar angle of 15.5 (2)° and a centroid-centroid distance of 4.73 (1) Å. One phenyl ring also forms a C - H⋯π contact to an adjacent imidazole ring, with an H⋯centroid distance of 3.18 Å.
TidsskriftActa Crystallographica. Section E: Structure Reports Online
Udgave nummer3
Sider (fra-til)619
StatusUdgivet - 1 mar. 2008
Eksternt udgivetJa

ID: 49635401