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(2S,4'R,5'R)-(E)-tert-Butyl 2-acetyl-2-(2-oxo-5-phenyl-1,3-dioxolan-4-ylmethyl)-5-phenylpent-4-enoate

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  • D.J. Fox
  • Daniel Sejer Pedersen
  • S. Warren
The title compound, C27H30O6, was prepared by monodihydroxylation of the bis-olefin (E,E)-tert-butyl 2-acetyl-2-cinnamyl-5-phenylpent-4-enoate using standard Sharpless asymmetric dihydroxylation conditions, followed by treatment with 1,1'-carbonyl diimidazole. In the crystal structure, the phenyl rings form an intramolecular edge-to-face C-H contact with an interplanar angle of 56.4° and a Hcentroid distance of 3.03 Å.
OriginalsprogEngelsk
TidsskriftActa Crystallographica. Section E: Structure Reports Online
Vol/bind64
Udgave nummer2
Sider (fra-til)530
ISSN1600-5368
DOI
StatusUdgivet - 1 feb. 2008
Eksternt udgivetJa

ID: 49636020