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Absolute rate constants for the reaction of NO3 radicals with a series of dienes at 295 K

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The rate constants for the reaction of NO3 radicals with a series of 7 dienes, 1,3-butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, trans-1,3-pentadiene, cis-1,3-pentadiene, trans,trans-2,4-hexadiene, and 1,3-cyclohexadiene, were measured at 295 K and at a total pressure of 1 atm. The rate constant were obtained using the absolute technique of pulse radiolysis combined with kinetic UV-VIS spectroscopy. The results are discussed in terms of reactivity trends and previous literature data.

OriginalsprogEngelsk
TidsskriftChemical Physics Letters
Vol/bind200
Udgave nummer3
Sider (fra-til)224-229
Antal sider6
ISSN0009-2614
DOI
StatusUdgivet - 4 dec. 1992

ID: 228196707