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Exciton Coupling in Circular Dichroic Spectroscopy as a Tool for Establishing the Absolute Configuration of alpha,beta-Unsaturated Esters of Allylic Alcohols

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alpha-beta-Unsaturated esters of allylic alcohols have been shown to exhibit exciton coupling by circular dichroic spectroscopy. This coupling permits the establishment of the absolute configuration. The method was used to prove the absolute configuration at C-2 of archangelolide. Detailed NMR spectral studies of the prepared model structures may be used as a reference for stereoisomeric guaianolides.
OriginalsprogUdefineret/Ukendt
TidsskriftActa Chemica Scandinavica. Supplementum
Vol/bind45
Udgave nummer1
Sider (fra-til)56-62
Antal sider7
ISSN0065-1133
DOI
StatusUdgivet - 1991

    Forskningsområder

  • sesquiterpenic lactones laser-trilobum terpenes stereochemistry thapsigargin

ID: 38061809