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Exo-metal coordination by a tricyclic [(P(mu-N-2-NC5H4))2(mu-O)]2 dimer in [(P(mu-N-2-NC5H4))2(mu-O)]2(CuCl x (C5H5N)2)4 (2-NC5H4 = 2-pyridyl, C5H5N = pyridine)

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  • Bond, Andrew
  • Emma L Doyle
  • Felipe García
  • Richard A Kowenicki
  • Mary McPartlin
  • Lucía Riera
  • Dominic S Wright
The in situ reaction of the phosphazane dimer [CIP(mu-N-2-NC5H4)]2 (2) with CuCl in the presence of CsH5N/H2O gives the title complex [(P(mu-N-2-NC5H4))2(mu-O)]2(CuCl x (C5H5N)2)4 (1), containing a tricyclic [(P(mu-N-2-NC5H4))2(mu-O)]2 ligand which is isoelectronic with species of the type [(P(mu-NR))2NR]2.
OriginalsprogEngelsk
TidsskriftChemical Communications
Udgave nummer24
Sider (fra-til)2990-1
Antal sider2
ISSN1359-7345
StatusUdgivet - 21 dec. 2003
Eksternt udgivetJa

ID: 46275922