Forskning ved Københavns Universitet - Københavns Universitet


Highly efficient and irreversible removal of cadmium through the formation of a solid solution

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningfagfællebedømt

  • Wang, Chen
  • Hui Yin
  • Lei Bi
  • Jing Su
  • Meiyi Zhang
  • Tao Lyu
  • Mick Cooper
  • Gang Pan
Sulfur-containing materials are very attractive for the efficient decontamination of some heavy metals. However, the effective and irreversible removal of Cd2+, coupled with a high uptake efficiency, remains a great challenge due to the relatively low bond dissociation energy of CdS. Herein, we propose a new strategy to overcome this challenge, by the incorporation of Cd2+ into a stable ZnxCd1-xS solid solution, rather than into CdS. This can be realised through the adsorption of Cd2+ by ZnS nanoparticles, which have exhibited a Cd2+ uptake capacity of approximate 400 mg g−1. Through this adsorption mechanism, the Cd2+ concentration in a contaminated solution could effectively be reduced from 50 ppb to <3 ppb, a WHO limit acceptable for drinking water. In addition, ZnS continued to exhibit this noteworthy uptake capacity even in the presence of Cu2+, Pb2+, and Hg2+. ZnS displayed high chemical stability. Particles aged in air for 3 months still retained a> 80% uptake capacity for Cd2+, compared with only 9% uptake capacity for similarly-aged FeS particles. This work reveals a new mechanism for Cd2+ removal with ZnS and establishes a valuable starting point for further studies into the formation of solid solutions for hazardous heavy metal removal applications.
TidsskriftJournal of Hazardous Materials
StatusUdgivet - 2020
Eksternt udgivetJa

ID: 229782079