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pH-induced structural forms of cyanidin and cyanidin 3-O-β-glucopyranoside

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningfagfællebedømt

Standard

pH-induced structural forms of cyanidin and cyanidin 3-O-β-glucopyranoside. / Rakić, Violeta; Rinnan, Åsmund; Polak, Tomaž; Skrt, Mihaela; Miljković, Milena; Ulrih, Nataša Poklar.

I: Dyes and Pigments, Bind 165, 2019, s. 71-80.

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningfagfællebedømt

Harvard

Rakić, V, Rinnan, Å, Polak, T, Skrt, M, Miljković, M & Ulrih, NP 2019, 'pH-induced structural forms of cyanidin and cyanidin 3-O-β-glucopyranoside', Dyes and Pigments, bind 165, s. 71-80. https://doi.org/10.1016/j.dyepig.2019.02.012

APA

Rakić, V., Rinnan, Å., Polak, T., Skrt, M., Miljković, M., & Ulrih, N. P. (2019). pH-induced structural forms of cyanidin and cyanidin 3-O-β-glucopyranoside. Dyes and Pigments, 165, 71-80. https://doi.org/10.1016/j.dyepig.2019.02.012

Vancouver

Rakić V, Rinnan Å, Polak T, Skrt M, Miljković M, Ulrih NP. pH-induced structural forms of cyanidin and cyanidin 3-O-β-glucopyranoside. Dyes and Pigments. 2019;165:71-80. https://doi.org/10.1016/j.dyepig.2019.02.012

Author

Rakić, Violeta ; Rinnan, Åsmund ; Polak, Tomaž ; Skrt, Mihaela ; Miljković, Milena ; Ulrih, Nataša Poklar. / pH-induced structural forms of cyanidin and cyanidin 3-O-β-glucopyranoside. I: Dyes and Pigments. 2019 ; Bind 165. s. 71-80.

Bibtex

@article{b10925b2a3e8446392caada3ff7937a6,
title = "pH-induced structural forms of cyanidin and cyanidin 3-O-β-glucopyranoside",
abstract = "The structural forms of cyanidin and cyanidin 3-O-β-glucopyranoside (Cy3Glc) were investigated in the pH range from 0.4 to 13.5 for cyanidin and 0.4 to 13.2 for Cy3Glc. The 3-glucosidic substitution in cyanidin 3-O-β-glucopyranoside at pH values lower than 4.0 was manifested in a large hyperchromic effect, while at pH values higher than 4.0 had the opposite effect and resulted in high hypochromic effect. Multivariate data analysis showed that the structural forms of cyanidin and Cy3Glc have numerous bends, which mutually overlap and influence the shape, position, and intensity of their spectrophotometric measurements. For cyanidin seven structural forms were identified, while for Cy3Glc six structural forms were identified, and one was not. To determine the stability of cyanidin and Cy3Glc at different pHs, HPLC–DAD–ESI/MS analysis was performed. The stability was tested in buffers at four pH values between 2 and 9. Degradation products formed from cyanidin and Cy3Glc at different time in the different buffer solutions were tracked and some of them were identified. Cyanidin stability was decreased in the following order pH 7.0, pH 4.0, pH 2.0, pH 9.0. Stability of Cy3Glc was increasing with decreasing the pH. Cy3Glc was the most stable at pH 2.0, and the least stable at pH 9.0.",
keywords = "Anthocyanins, Cyanidin, Cyanidin (PubChem CID: 68247), Cyanidin 3-O-β-glucopyranoside, Cyanidin 3-O-β-glucopyranoside (PubChem CID: 197081), HPLC-ESI/MS",
author = "Violeta Raki{\'c} and {\AA}smund Rinnan and Toma{\v z} Polak and Mihaela Skrt and Milena Miljkovi{\'c} and Ulrih, {Nata{\v s}a Poklar}",
year = "2019",
doi = "10.1016/j.dyepig.2019.02.012",
language = "English",
volume = "165",
pages = "71--80",
journal = "Dyes and Pigments",
issn = "0143-7208",
publisher = "Pergamon Press",

}

RIS

TY - JOUR

T1 - pH-induced structural forms of cyanidin and cyanidin 3-O-β-glucopyranoside

AU - Rakić, Violeta

AU - Rinnan, Åsmund

AU - Polak, Tomaž

AU - Skrt, Mihaela

AU - Miljković, Milena

AU - Ulrih, Nataša Poklar

PY - 2019

Y1 - 2019

N2 - The structural forms of cyanidin and cyanidin 3-O-β-glucopyranoside (Cy3Glc) were investigated in the pH range from 0.4 to 13.5 for cyanidin and 0.4 to 13.2 for Cy3Glc. The 3-glucosidic substitution in cyanidin 3-O-β-glucopyranoside at pH values lower than 4.0 was manifested in a large hyperchromic effect, while at pH values higher than 4.0 had the opposite effect and resulted in high hypochromic effect. Multivariate data analysis showed that the structural forms of cyanidin and Cy3Glc have numerous bends, which mutually overlap and influence the shape, position, and intensity of their spectrophotometric measurements. For cyanidin seven structural forms were identified, while for Cy3Glc six structural forms were identified, and one was not. To determine the stability of cyanidin and Cy3Glc at different pHs, HPLC–DAD–ESI/MS analysis was performed. The stability was tested in buffers at four pH values between 2 and 9. Degradation products formed from cyanidin and Cy3Glc at different time in the different buffer solutions were tracked and some of them were identified. Cyanidin stability was decreased in the following order pH 7.0, pH 4.0, pH 2.0, pH 9.0. Stability of Cy3Glc was increasing with decreasing the pH. Cy3Glc was the most stable at pH 2.0, and the least stable at pH 9.0.

AB - The structural forms of cyanidin and cyanidin 3-O-β-glucopyranoside (Cy3Glc) were investigated in the pH range from 0.4 to 13.5 for cyanidin and 0.4 to 13.2 for Cy3Glc. The 3-glucosidic substitution in cyanidin 3-O-β-glucopyranoside at pH values lower than 4.0 was manifested in a large hyperchromic effect, while at pH values higher than 4.0 had the opposite effect and resulted in high hypochromic effect. Multivariate data analysis showed that the structural forms of cyanidin and Cy3Glc have numerous bends, which mutually overlap and influence the shape, position, and intensity of their spectrophotometric measurements. For cyanidin seven structural forms were identified, while for Cy3Glc six structural forms were identified, and one was not. To determine the stability of cyanidin and Cy3Glc at different pHs, HPLC–DAD–ESI/MS analysis was performed. The stability was tested in buffers at four pH values between 2 and 9. Degradation products formed from cyanidin and Cy3Glc at different time in the different buffer solutions were tracked and some of them were identified. Cyanidin stability was decreased in the following order pH 7.0, pH 4.0, pH 2.0, pH 9.0. Stability of Cy3Glc was increasing with decreasing the pH. Cy3Glc was the most stable at pH 2.0, and the least stable at pH 9.0.

KW - Anthocyanins

KW - Cyanidin

KW - Cyanidin (PubChem CID: 68247)

KW - Cyanidin 3-O-β-glucopyranoside

KW - Cyanidin 3-O-β-glucopyranoside (PubChem CID: 197081)

KW - HPLC-ESI/MS

U2 - 10.1016/j.dyepig.2019.02.012

DO - 10.1016/j.dyepig.2019.02.012

M3 - Journal article

AN - SCOPUS:85061548495

VL - 165

SP - 71

EP - 80

JO - Dyes and Pigments

JF - Dyes and Pigments

SN - 0143-7208

ER -

ID: 216209629