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Rate constants for the gas-phase reactions of OH radicals and Cl atoms with CH3CH2NO2, CH3CH2CH2NO2, CH3CH2CH2CH2NO2, and CH3CH2CH2CH2CH2NO2

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Rate constants for the reactions of OH radicals and Cl atoms with CH3CH2NO2, CH3CH2CH2NO2, CH3CH2CH2CH2NO2, and CH3CH2CH2CH2CH2NO2 have been determined at 295±3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis combined with kinetic spectroscopy and a conventional photolytic relative rate method. The Cl rate constants were measured using only the relative rate method. The results are discussed in terms of reactivity trends.

OriginalsprogEngelsk
TidsskriftChemical Physics Letters
Vol/bind156
Udgave nummer4
Sider (fra-til)312-318
Antal sider7
ISSN0009-2614
DOI
StatusUdgivet - 7 apr. 1989

ID: 214272635