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Setting the anomeric effect against steric effects in simple acyclic acetals. Non-anomeric non-classical conformations. An n.m.r. and molecular mechanics investigation

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N.m.r. parameters for a series of simple aliphatic acetals indicate that the preferred conformation changes from the anomeric one found in formaldehyde dimethyl acetal (formal), to a new one whose structure is suggested by molecular mechanics calculations.
OriginalsprogUdefineret/Ukendt
TidsskriftChemical communications (Cambridge, England)
Vol/bind1987
Sider (fra-til)554-555
Antal sider2
ISSN1359-7345
DOI
StatusUdgivet - 1987

ID: 38493951