Syntheses and magnetic properties of hexanuclear [Cp2Mn3(L1)4]2 and octanuclear [Mn8(L2)12(mu 4-O)2] (L1 = 2-HNC5H5N, L2 = 2-NH-3-Br-5-MeC5H3N, Cp = C5H5)
Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
Carmen Soria Alvarez, Andrew D Bond, Dale Cave, Marta E G Mosquera, Eilís A Harron, Richard A Layfield, Mary McPartlin, Jeremy M Rawson, Paul T Wood, Dominic S Wright
The reactions of manganocene, Cp2Mn, with 2-aminopyridine (L1H) or 2-amino-3-bromo-5-methylpyridine (L2H) give the novel hexanuclear and octanuclear Mn(II) amido cage compounds [Cp2Mn3(L1)4]2 (1) and [Mn8(L2)12(mu 4-O)2] (2); magnetic measurements on which provide a rare insight into the magnetic properties of amido-bridged metal clusters.
| Originalsprog | Engelsk |
|---|---|
| Tidsskrift | Chemical Communications |
| Tidsskriftsnummer | 24 |
| Sider (fra-til) | 2980-1 |
| Antal sider | 2 |
| ISSN | 1359-7345 |
| Status | Udgivet - 21 dec. 2002 |
| Eksternt udgivet | Ja |
ID: 46374729
