Forskning ved Københavns Universitet - Københavns Universitet

Forside

Syntheses of syn and anti doublebent [5]phenylene

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningfagfællebedømt

  • Dennis T-Y Bong
  • Eugene W L Chan
  • Rainer Diercks
  • Peter I Dosa
  • Michael M Haley
  • Adam J Matzger
  • Ognjen S Miljanić
  • K Peter C Vollhardt
  • Bond, Andrew
  • Simon J Teat
  • Amnon Stanger
[structure: see text] The parent and dipropyl-substituted anti (1a,b) and syn doublebent (2a,b) [5]phenylenes have been assembled by CpCo-catalyzed double cyclization of regiospecifically constructed appropriate hexaynes. (1)H NMR, NICS, and an X-ray structural analysis of 1a reflect the aromatizing effect of double angular fusion on the central ring of the linear [3]phenylene substructure.
OriginalsprogEngelsk
TidsskriftOrganic Letters
Vol/bind6
Udgave nummer13
Sider (fra-til)2249-52
Antal sider4
ISSN1523-7060
DOI
StatusUdgivet - 24 jun. 2004
Eksternt udgivetJa

ID: 46282880