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Synthesis and structure of [(Sn(mu-PCy))3(Na x PMDETA)2], containing an electron-deficient [(Sn(mu-PCy))3]2- dianion

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  • Paula Alvarez-Bercedo
  • Bond, Andrew
  • Robert Haigh
  • Alexander D Hopkins
  • Gavin T Lawson
  • Mary McPartlin
  • David Moncrieff
  • Marta E Gonzalez Mosquera
  • Jeremy M Rawson
  • Anthony D Woods
  • Dominic S Wright
The reaction of CyPHNa with Sn(NMe2)2 in the presence of PMDETA (= (Me2NCH2CH2)2NMe) gives the title compound [(Sn(mu-PCy))3(Na x PMDETA)2] (1), containing an electron-deficient [(Sn(mu-PCy))]3(2-) dianion with a novel two-electron, three centre (2e-3c) bonding arrangement.
OriginalsprogEngelsk
TidsskriftChemical Communications
Udgave nummer11
Sider (fra-til)1288-9
Antal sider2
ISSN1359-7345
StatusUdgivet - 7 jun. 2003
Eksternt udgivetJa

ID: 46282542