Synthesis and structure of [(Sn(mu-PCy))3(Na x PMDETA)2], containing an electron-deficient [(Sn(mu-PCy))3]2- dianion
Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
The reaction of CyPHNa with Sn(NMe2)2 in the presence of PMDETA (= (Me2NCH2CH2)2NMe) gives the title compound [(Sn(mu-PCy))3(Na x PMDETA)2] (1), containing an electron-deficient [(Sn(mu-PCy))]3(2-) dianion with a novel two-electron, three centre (2e-3c) bonding arrangement.
| Originalsprog | Engelsk |
|---|---|
| Tidsskrift | Chemical Communications |
| Udgave nummer | 11 |
| Sider (fra-til) | 1288-9 |
| Antal sider | 2 |
| ISSN | 1359-7345 |
| Status | Udgivet - 7 jun. 2003 |
| Eksternt udgivet | Ja |
ID: 46282542
